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It doesn't reflect (bounce off); it refracts (bends). You can see rainbows only when the sun is shining behind you and it is raining in front of you. Rainbows form when sunlight shines through millions of raindrops. Sunlight is a mixture of colours. When it passes through a raindrop, it is refracted (bent) and the light splits and spreads into seven colours.
Since children sometimes learn concepts like this by doing, here is a link to an experiment to make a rainbow. Have fun!
http://www.first-school.ws/activities/science/rainbow-experiment.htm
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How is a rainbow created
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How do I explain how a rainbow is created in a way that a toddler will understand the explanation?